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M A T E R I A L  S A F E T Y  D A T A  S H E E T  E Q U A L- NUTRA  SWEET



  Product Number:  858900

  Product Name:  L-Aspartyl-L-phenylalanine methyl ester, 96%



  Description / Pricing

  Cert. of Analysis

  MSDS



  Valid 02/2000 - 04/2000



  Aldrich Chemical Co., Inc.

  1001 West St. Paul

  Milwaukee, WI 53233 USA

  Tel: 414-273-3850





              M A T E R I A L  S A F E T Y  D A T A  S H E E T



  SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - -





  CATALOG #: 858900



NAME:        L-ASPARTYL-L-PHENYLALANINE METHYL ESTER, 96%



SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS





  CAS #: 22839-47-0



    MF: C14H18N2O5



   EC NO:  245-261-3   SYNONYMS



3-AMINO-N-(ALPHA- CARBOXYPHENETHYL)SUCCINAMIC ACID N-METHYL ESTER,



    STEREOISOMER * ASPARTAME * ASPARTYLPHENYLALANINE METHYL ESTER *  N-L-



      ALPHA-ASPARTYL-L-PHENYLALANINE 1-METHYL ESTER * CANDEREL *  DIPEPTIDE



      SWEETENER * EQUAL * METHYL ASPARTYLPHENYLALANATE * 1-METHYL

  N-L-  ALPHA-



  ASPARTYL-L-PHENYLALANINE * NUTRASWEET * L-PHENYLALANINE, N-L-ALPHA-

      ASPARTYL-, 1-METHYL ESTER (9CI) * SWEET DIPEPTIDE *



SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - -



LABEL PRECAUTIONARY STATEMENTS



HARMFUL



POSSIBLE SENSITIZER.



WEAR SUITABLE PROTECTIVE CLOTHING.



SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - -



IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS OF AMOUNTS WATER 
FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH 
SOAP AND COPIOUS AMOUNTS OF WATER.



IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.



IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE.



SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - -



    EXTINGUISHING MEDIA



      WATER SPRAY.



CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.



    SPECIAL FIREFIGHTING PROCEDURES

WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

PREVENT CONTACT WITH SKIN AND EYES.



UNUSUAL FIRE AND EXPLOSIONS HAZARDS

EMITS TOXIC FUMES UNDER FIRE CONDITIONS.



SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - -



WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER 
GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.    AVOID 
RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS 
COMPLETE.



SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - -



  REFER TO SECTION 8.



SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - -



CHEMICAL SAFETY GOGGLES.

COMPATIBLE CHEMICAL-RESISTANT GLOVES.

NIOSH/MSHA-APPROVED RESPIRATOR.

SAFETY SHOWER AND EYE BATH.

MECHANICAL EXHAUST REQUIRED.

AVOID INHALATION.

AVOID CONTACT WITH EYES, SKIN AND CLOTHING.

AVOID PROLONGED OR REPEATED EXPOSURE.

WASH THOROUGHLY AFTER HANDLING.

POSSIBLE SENSITIZER.

KEEP TIGHTLY CLOSED.

STORE IN A COOL DRY PLACE.



SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - -



APPEARANCE AND ODOR

WHITE POWDER

PHYSICAL PROPERTIES

MELTING POINT:      248 C TO 250 C



SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - 
-   INCOMPATIBILITIES

STRONG OXIDIZING AGENTS

HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

TOXIC FUMES OF:

CARBON MONOXIDE, CARBON DIOXIDE

NITROGEN OXIDES



SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - -



ACUTE EFFECTS



MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION.

MAY CAUSE EYE IRRITATION.

MAY CAUSE SKIN IRRITATION.

PROLONGED OR REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN 
CERTAIN      SENSITIVE INDIVIDUALS.

TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL 
PROPERTIES HAVE NOT BEEN THOROUGHLY

INVESTIGATED.



ADDITIONAL INFORMATION

WARNING TO PERSONS WITH PHENYLKETONURIA! THIS MATERIAL CAN RELEASE 
PHENYLALANINE.

   RTECS #: WM3407000



SUCCINAMIC ACID, 3-AMINO-N-(ALPHA-CARBOXYPHENETHYL)-, N-METHYL ESTER,

STEREOISOMER



TOXICITY DATA



ORL-RAT LD50:>10 GM/KG TOVEFN (3),37,1996



IPR-RAT LD50:>5 GM/KG TOVEFN (3),37,1996



ORL-MUS LD50:>10 GM/KG TOVEFN (3),37,1996



IPR-MUS LD50:>5 GM/KG TOVEFN (3),37,1996



TARGET ORGAN DATA



SKIN AND APPENDAGES (AFTER SYSTEMIC EXPOSURE: DERMATITIS, ALLERGIC)

ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE 
INFORMATION.



SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - -

DATA NOT YET AVAILABLE.



SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - -



DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A

CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.









SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - -



CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.



SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - -

EUROPEAN INFORMATION HARMFUL

S 36

WEAR SUITABLE PROTECTIVE CLOTHING.

REVIEWS, STANDARDS, AND REGULATIONS

OEL=MAK

EPA TSCA SECTION 8(B) CHEMICAL INVENTORY NIOSH ANALYTICAL METHOD, 1994: 
ASPARTAME, 5031

NTP CARCINOGENESIS STUDIES; SELECTED, SEPTEMBER 1999



SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - -

THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR 
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

COPYRIGHT 1999 SIGMA-ALDRICH CO.
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